if it has a good pedal i wouldn't think bleeding the brakes would do much, but it is easy enough to do, so trying it would be too much to do....
i can't speak to replacing tons of those sealed hub/bearing assemblies, but the 3 trucks (2 of those 3500 CV's, all of them went passed 100,000 and the replacements over 150,000....but again, that doesnt mean its not a bad bearing...my Cargo Max has 118,000 on it right now, i was going to go 150,000 and replace them as a "preventive" deal, but more since i will be doing a bunch of maintainace at 125,000 and be oos to do it, chances are ill replace them then.
Even though all the hardware came with the new calipers, if you didn't lube the slides and the bolts, you could still have caliper hanging up...the anti lock wheel sensor / vane is part of the hub assembly....so to change it, you need to change the hub....and if you do 1 hub, do them both....for that van, youcan get good ones for about $85 a piece...and you already know how to get the rotor off the hub...